Thermodynamic and exergoeconomic evaluation of waste heat recovery for hydrogen production in a CCHP system

Document Type : Research Paper

Author

Mechanical Engineering Department, Ayatollah Boroujerdi University, Boroujerd, Iran

Abstract

This study presents the energy, exergy, and economic evaluation of recovering energy from a modified Kalina power-cooling system to provide heating and hydrogen. An ORC is employed to use the waste heat of the Kalina cycle, and the generated power is transmitted to a PEM electrolyzer for hydrogen production. Furthermore, the waste heat of the separator outlet is recovered through a new heat exchanger to provide heating. The results show that the proposed system can produce 317 kW power, 714.7 kW cooling, 50.3 kW heating, and 4.491 kg/h hydrogen. Moreover, the exergoeconomic analysis indicates that the PEM electrolyzer, the cascade heat exchanger, and the vapor generator have the highest cost rate among the system components. Additionally, a parametric study was performed on the system to investigate the variation of some key parameters, including the maximum operating pressure, separator II pressure, ammonia mass fraction in a basic solution, and pinch point temperature difference in the cascade heat exchanger for the thermodynamic and economic performance of the system.  

Keywords

Main Subjects


 
[1]        E. Akrami, A. Nemati, H. Nami, F. Ranjbar, Exergy and exergoeconomic assessment of hydrogen and cooling production from concentrated PVT equipped with PEM electrolyzer and LiBr-H2O absorption chiller, International Journal of Hydrogen Energy, 43(2), 622-633, 2018.
[2]        J. Han, X. Wang, J. Xu, N. Yi, S. S. Ashraf Talesh, Thermodynamic analysis and optimization of an innovative geothermal-based organic Rankine cycle using zeotropic mixtures for power and hydrogen production, International Journal of Hydrogen Energy, 45(15), 8282-8299, 2020.
[3]        N. Sarabchi, S. M. S. Mahmoudi, M. Yari, A. Farzi, Exergoeconomic analysis and optimization of a novel hybrid cogeneration system: High-temperature proton exchange membrane fuel cell/Kalina cycle, driven by solar energy, Energy Conversion and Management, 190, 14-33, 2019.
[4]        M. Ni, M. K. H. Leung, K. Sumathy, D. Y. C. Leung, Potential of renewable hydrogen production for energy supply in Hong Kong, International Journal of Hydrogen Energy, 31(10), 1401-1412, 2006.
[5]        J. Nowotny, T. Hoshino, J. Dodson, A. J. Atanacio, M. Ionescu, V. Peterson, K. E. Prince, M. Yamawaki, T. Bak, W. Sigmund, T. N. Veziroglu, M. A. Alim, Towards sustainable energy. Generation of hydrogen fuel using nuclear energy, International Journal of Hydrogen Energy, Vol. 41(30), 12812-12825, 2016.
[6]        H. Kianfard, S. Khalilarya, S. Jafarmadar, Exergy and exergoeconomic evaluation of hydrogen and distilled water production via combination of PEM electrolyzer, RO desalination unit and geothermal driven dual fluid ORC, Energy Conversion and Management,177, 339-349, 2018.
[7]        H. Nami, F. Mohammadkhani, F. Ranjbar, Utilization of waste heat from GTMHR for hydrogen generation via combination of organic Rankine cycles and PEM electrolysis, Energy Conversion and Management, 127, 589-598, 2016.
[8]        S. Yosaf, H. Ozcan, Exergoeconomic investigation of flue gas driven ejector absorption power system integrated with PEM electrolyser for hydrogen generation, Energy, 163, 88-99, 2018.
[9]        H. Nami, E. Akrami, F. Ranjbar, Hydrogen production using the waste heat of Benchmark pressurized Molten carbonate fuel cell system via combination of organic Rankine cycle and proton exchange membrane (PEM) electrolysis, Applied Thermal Engineering, 114, 631-638, 2017.
[10]      O. Bamisile, Q. Huang, M. Dagbasi, V. Adebayo, E. C. Okonkwo, P. Ayambire, T. Al-Ansari, T. A. H. Ratlamwala, Thermo-environ study of a concentrated photovoltaic thermal system integrated with Kalina cycle for multigeneration and hydrogen production, International Journal of Hydrogen Energy, 45(51), 26716-26732, 2020.
[11]      B. Kurşun, K. Ökten, Thermodynamic analysis of a Rankine cycle coupled with a concentrated photovoltaic thermal system for hydrogen production by a proton exchange membrane electrolyzer plant, International Journal of Hydrogen Energy, 44(41),22863-22875, 2019.
[12]      M. Ni, M. K. H. Leung, D. Y. C. Leung, Energy and exergy analysis of hydrogen production by a proton exchange membrane (PEM) electrolyzer plant, Energy Conversion and Management, 49(10), 2748-2756, 2008.
[13]      P. Ahmadi, I. Dincer, M. A. Rosen, Energy and exergy analyses of hydrogen production via solar-boosted ocean thermal energy conversion and PEM electrolysis, International Journal of Hydrogen Energy, 38(4), 1795-1805, 2013.
[14]      Z. Sun, J. Wang, Y. Dai, J. Wang, Exergy analysis and optimization of a hydrogen production process by a solar-liquefied natural gas hybrid driven transcritical CO2 power cycle, International Journal of Hydrogen Energy, 37(24), 18731-18739, 2012.
[15]      G. Fan, B. Yang, P. Guo, S. Lin, S. G. Farkoush, N. Afshar, Comprehensive analysis and multi-objective optimization of a power and hydrogen production system based on a combination of flash-binary geothermal and PEM electrolyzer, International Journal of Hydrogen Energy, 46(68), 33718-33737, 2021.
[16]      F. Musharavati, P. Ahmadi, S. Khanmohammadi, Exergoeconomic assessment and multiobjective optimization of a geothermal-based trigeneration system for electricity, cooling, and clean hydrogen production, Journal of Thermal Analysis and Calorimetry, 145(3), 1673-1689, 2021.
[17]      N. Chitgar, M. Moghimi, Design and evaluation of a novel multi-generation system based on SOFC-GT for electricity, fresh water and hydrogen production, Energy, 197, 117162, 2020.
[18]      J. Wang, J. Wang, P. Zhao, Y. Dai, Thermodynamic analysis of a new combined cooling and power system using ammonia–water mixture, Energy Conversion and Management, 117, 335-342, 2016.
[19]      J. Szargut, Exergy Method: Technical and Ecological Applications: WIT Press, 2005.
[20]      C. Lamy, From hydrogen production by water electrolysis to its utilization in a PEM fuel cell or in a SO fuel cell: Some considerations on the energy efficiencies, International Journal of Hydrogen Energy, 41(34),15415-15425, 2016.
[21]      J. A. Salva, A. Iranzo, F. Rosa, E. Tapia, Validation of cell voltage and water content in a PEM (polymer electrolyte membrane) fuel cell model using neutron imaging for different operating conditions, Energy, 101, 100-112, 2016.
[22]      F. I. Abam, T. A. Briggs, O. E. Diemuodeke, E. B. Ekwe, K. N. Ujoatuonu, J. Isaac, M. C. Ndukwu, Thermodynamic and economic analysis of a Kalina system with integrated lithium-bromide-absorption cycle for power and cooling production, Energy Reports, 6, 1992-2005, 2020.